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The structural design of self-healing materials determines the ultimate performance of the product that can be used in a wide range of applications. Incorporating intrinsic self-healing moieties into puncture-resistant materials could significantly improve the failure resistance and product longevity, since their rapidly rebuilt bonds will provide additional recovery force to resist the external force. Herein, we present a series of tailored urea-modified poly(dimethylsiloxane)-based self-healing polymers (U-PDMS-SPs) that exhibit excellent puncture-resistant properties, fast autonomous self-healing, multi-cycle adhesion capabilities, and well-tunable mechanical properties. Controlling the composition of chemical and physical cross-links enables the U-PDMS-SPs to have an extensibility of 528% and a toughness of 0.6 MJ m −3 . U-PDMS-SPs exhibit fast autonomous self-healability with 25% strain recovery within 2 minutes of healing, and over 90% toughness recovery after 16 hours. We further demonstrate its puncture-resistant properties under the ASTM D5748 standard with an unbreakable feature. Furthermore, the multi-cycle adhesive properties of U-PDMS-SPs are also revealed. High puncture resistance (>327 mJ) and facile adhesion with rapid autonomous self-healability will have a broad impact on the design of adhesives, roofing materials, and many other functional materials with enhanced longevity. 

The bathymetry under the Amery Ice Shelf steers the flow of ocean currents transporting ocean heat, and thus is a prerequisite for precise modeling of ice‐ocean interactions. However, hampered by thick ice, direct observations of sub‐ice‐shelf bathymetry are rare, limiting our ability to quantify the evolution of this sector and its future contribution to global mean sea level rise. We estimated the bathymetry of this region from airborne gravity anomaly using simulated annealing. Unlike the current model which shows a comparatively flat seafloor beneath the calving front, our estimation results reveal a 255‐m‐deep shoal at the western side and a 1,050‐m‐deep trough at the eastern side, which are important topographic features controlling the ocean heat transport into the sub‐ice cavity. The new model also reveals previously unknown depressions and sills that are critical to an improved modeling of the sub‐ice‐shelf ocean circulation and induced basal melting.